In 2005, she won the Wegman's Rochester LPGA. In 2006, her first round score of 62 in the Kraft Nabisco Championship tied the record for lowest score ever by a golfer, male or female, in any major tournament. Her playoff loss to Karrie Webb marked her best finish until 2007 in an LPGA major. By the end of the year she won six tournaments, topped the moneylist and claimed her first LPGA Tour Player of the Year award which goes to the player who gains the most number of points throughout the season based on a formula in which points are awarded for top-10 finishes and are doubled at the LPGA's four major championships and at the season-ending ADT Championship.She also won the LPGA Vare Trophy for lowest scoring average on the LPGA Tour.
Her achievements were recognized outside the sport of golf when Ochoa won the 2006 Associated Press Female Athlete of the Year award and received the National Sports Prize for the second time.
In April 2007, Ochoa overtook Annika Sörenstam to become World number one ranked golfer.
In August 2007, Ochoa won her first major championship at the historic home of golf, the Old Course at St. Andrews, with a wire-to-wire win by four shots at the Women's British Open. She won the next two LPGA events, the CN Canadian Women's Open and the Safeway Classic, the first to win three consecutive events since Annika Sörenstam in 2005.
Also in 2007, Ochoa became the first woman ever to earn more than $3,000,000 in a single season, surpasing Annika Sorenstam's previous record of $2,863,904.
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